The Holocene sea-ice project brings together for the first time, records from the Antarctic continent and deep sea sediments that will allow us to calibrate three sea-ice extent surrogates, validate their use in contrast to satellite observations and explore climatic influence on the physio-ecological environment over the last 10,000 years. Spreadsheet 1 (appendix A): Complete list of Accelerator Mass Spectrometry (AMS) dating completed on E27-23 from various identified sources with original 14CAge and reported error. Three dates identified as Burckle pers comm. here were provided by Dr Lloyd Burckle (LDEO) to Dr L. Armand for this work. Outlier attributions are identified; the term Averaged identifies the two samples where final calibrated dates were averaged in this work. All remaining AMS dates were converted to calendar ages using the linear-based CALIB07 (Stuiver and Reimer, 1993) with calibration to the Marine13 dataset (Reimer et al., 2013) at 95% confidence (sigma 2) and included a correction for the surface water reservoir age of ~752 years at the site of core E27-23 resolved from the marine radiocarbon reservoir correction database and software available from http://radiocarbon.LDEO.columbia.edu/ (Butzin et al., 2005). The percent Marine Carbon relative attribution is provided. The Median age (Cal Yr BP) used as the final age at each respective (mid) depth is provided. In Appendix A the dates are all ages in years, however some are uncalibrated ages and others are Cal yr BP (= calendar years before present). So in terms of headings in Table A: Raw 14C age yr BP - is the raw age provided by radiocarbon dating without any corrections applied. It is in years before present. Corrected raw age (RA=752) - is the raw age with a local RA (Reservoir Age) correction applied and is still in years before present. The remaining ages are calendar years before present having been calibrated. All formats follow recommendations for reporting raw 14C dates and their calibration ages. Spreadsheet 2 (appendix B): Comparison of calibration output from the input of accepted 14C dates using OXCAL 4.2 (Bronk Ramsey 2009; Blaauw 2010), and CALIB07 (Stuiver and Reimer, 1993), both using the Marine13 calibration curve (Reimer et al., 2013) at 95.4% confidence (sigma 2) and including a correction for the surface water reservoir age of ~752 years at the site of core E27-23. The calibration output difference between the median Cal Yr BP, regardless of calibration method employed, was greater than or equal to 40 Cal Yr BP. Calibration data from the output of CALIB07 has been used in this paper to determine chronostratigraphy. Spreadsheet 3 (appendix C): The foraminiferal stable isotope data from E27-23. Ratios of oxygen (delta 18O) measured from the planktonic foraminifer Neogloboquadrina pachyderma sinistral (greater than 150 microns). Isotope values are reported as per mil (%) deviations relative to the Vienna Peedee Belemnite (VPDB). Spreadsheet 4 (appendix D): The paleo winter sea-ice concentration (wSIC) estimates for marine sediment core SO136-111. The calendar ages, in thousands of years before present (kyr BP), are provided for each sample from core SO136-111. For each of the samples in core SO136-111, we have provided the estimates winter sea-ice concentration (%), along with the associated lower and upper bounds for the 95% confidence interval around the estimated winter sea-ice concentration (%), for both GAM/WSI/13 and GAM/WSI/ETS. The final two columns provide the estimated average annual monthly sea-ice cover for each sample within core SO136-111, originally estimated using the Modern Analogue Technique, by Crosta et al. (2004). Finally, we provide the estimated summer sea surface temperature, again using the Modern Analogue Technique, from Crosta et al. 2004. Spreadsheet 5 (appendix E): The paleo wSIC estimates for marine sediment core E27-23. The calendar ages, in thousands of years before present are provided for each sample from core E27-23. For each of the samples in core E27-23, we have provided the estimated winter sea-ice concentration (%), along with the associated lower and upper bounds for the 95% confidence interval around the estimates for winter sea-ice concentration (%).

Prediction of future climate change requires knowledge of past changes. Polar snow forms an archive of environmental conditions that is accessible by drilling and analysing ice cores. This project uses ice core data to reconstruct records, including past temperature and atmospheric composition, to improve understanding of the climate system. Report from the 2007/2008 season This proposal encompasses the laboratory-based component of ice core research at the Australian Antarctic Division. The project is principally focused on analysis of currently archived ice core material but will include analysis of new cores (to be collected in future field activities that will be the subject of separate research proposals through the duration of the project). This work is conducted as part of the ACE-CRC (Antarctic Climate and Ecosystems Cooperative Research Centre). The overall general aim for this AAS project is to understand past climate variability and change, through the study of Antarctic ice cores. More specifically, this research explores the role of Antarctica in hemispheric and global climate, with particular emphasis on climate variability and change in the Southern Ocean, mid-latitudes, and the Australian sector. To effectively achieve this aim, we have defined four research questions, broadly based on a separation at different temporal and spatial scales: 1. What do high resolution comparisons of instrumental climate data and ice cores reveal about calibration of ice core signals and underlying mechanisms? 2. What is the spatial and temporal variability in climate across the wider East Antarctic region in the last few centuries, particularly spanning the onset of anthropogenic influence? How is this connected with overall variability in the Antarctic, and the Southern Ocean, particularly the Australian sector? 3. What changes and modes of variability are seen in Holocene Antarctic and Southern Ocean climate from high resolution ice cores? 4. What climate changes were seen in coastal Antarctica through the last glacial and deglaciation, and how does the timing compare with other records, especially the Northern Hemisphere records? Feeding into these research questions are a number of specific scientific objectives (listed below, with clearly identified methodology to achieve outcomes). These objectives address issues essential to a number of research fields across the Australian Antarctic program (see 3.1.3), and have been identified through knowledge gained from the earlier AAS project 757 and the scientific literature (discussed in more detail in section 3.1.2). Research will use high-resolution ice core studies as a tool to probe climate variability on timescales from seasonal through to millennial. This ability to access very high resolution climate records through ice cores is of major importance because it is the only means of calibrating the ice core recorder against observed meteorology. Also, the seasonal- to interannual-timescales capture climate variability that is not readily probed in other records. The high snow accumulation on Law Dome, combined with a 1.2km thick ice sheet, provides a unique high resolution record of the Holocene and access to the last Glacial-interglacial cycle. The main objectives are listed below, with a brief explanation of the methodology employed to achieve these objectives: - Extend the time-series of ice core chemical and physical measurements - Focussed on East Antarctic sites, (particularly Law Dome). The length and resolution of records so far obtained will be increased and the range of measured parameters increased. This includes from the DSS core: completion of a full 90 thousand year record of trace ion data to accompany the completed d18O isotope series; high-resolution (subannual) series for trace ions and d18O over the last 2000 years; new measurements including d13CH4 (and potentially dCH3D) in collaboration with University of Colorado, NIWA and CSIRO and deuterium excess measurements using new mass-spectrometry facilities. - Calibrate ice core measurements against instrumental records - Calibrate ice core measurements against meteorological, and other proxy series, in order to better understand the climate signals in ice cores and to provide new proxies. This work will use ultra-high resolution data, especially through the period of instrumental overlap (for Antarctic records, this period covers the nearly 50 years since the first IGY). The study is expected to draw data from a field activity in 2008/09 summer in conjunction with IPY, which has a 'special observing period' for tracking airmasses arriving at ice core sites. - Investigate modes of climate variability - Investigate the strength, variability and alteration in modes of variability for specific climate processes, especially to examine any recent changes in these from Holocene background. In particular, processes or indices that will be explored include ENSO, the Southern Annular Mode, sea-ice extent, decadal variability in coupled ocean-atmosphere modes such as the Antarctic Circumpolar Wave (White and Peterson, 1996), atmospheric circulation indices (e.g. stratospheric markers such as nitrate or beryllium-10 and dust or trace-metal variations). - Examine response and sensitivity to forcing variations and explore mechanisms - This includes studies of: insolation links to climate variability, the timing and magnitude of major volcanic events, and variations associated with atmospheric composition changes (the '8200 BP' event, deglacial interhemispheric climate variations and abrupt changes in the last glacial). - Improve the understanding of the Antarctic climate system using multiple records - Explore relationships between the high resolution ice core records and other ice cores including the Antarctic interior to better understand both the spatial structure of the Antarctic climate system (including teleconnections), and the interpretation of the ice cores themselves. - Contribute to Antarctic mass-balance and sea-level rise - Derive records of accumulation input and variability for the last 100-200 years at sites in eastern Wilkes Land and for the last 90 thousand years at Law Dome. These records contribute to understanding Antarctic mass-balance and sea-level impacts. - Develop and maintain facilities and expertise for analysis of ice cores - Continue to develop and maintain facilities and expertise for analysis of ice cores and related climate studies. The facilities supported by this project provide a core capacity for downstream analysis and interpretation of Australian field studies, by the AAD, and also by collaborative partners in CSIRO, University of Newcastle, Curtin University of Technology as well as several important international partnerships. In the last 12 months, the project has predominantly been in a laboratory/measurement phase and so progress is predominantly against the first and last objectives at 1.1 (Extend time series, Develop facilities). The isotope and trace chemistry records for the Law Dome cores are being extended and in-filled where gaps occur. The time series have been extended. Most measurements have been undertaken using recently drilled new core material (DSS0506 from AAS2384), as this is providing an opportunity to derive new series (deuterium) and check existing data for inter-core fidelity. New core material which brings records up to January 2008 has been analysed and the data are being combined with other cores to provide continuous series. For the interpretive objectives, progress consists predominantly of results that have so far been presented at various meetings. We now have new data that strongly mitigate against the "EPICA hypothesis" that posits that sea-salts in ice cores (particularly inland cores) are specifically connected with sea-ice extent. We are able to quantify the degree of influence of sea-ice surface as a source of salt and demonstrate that it decreases with distance from the coast. We have further investigated the snowfall accumulation at Law Dome and are probing links seen to rainfall in Southwest Western Australia. We have also investigated subannual variations in snowfall accumulation and find that winter accumulation variability dominates the annual signal. We have new results from very high resolution studies of beryllium-10 which demonstrate a shorter atmospheric residence time for this cosmogenically produced species than has been accepted. This work has potential to improve the use of beryllium-10 as a proxy for solar variability and has implications for understanding of atmospheric transport. Taken from the 2008-2009 Progress Report: Progress against objectives: This year's activities have been focused upon data generation and also with associated fieldwork for AAS 3025 (Aurora Basin North Ice Core Drilling). A deliberate slowing of progress on AAS 757 this year was planned because of a large investment of personnel time toward AAS 3025, however good progress has nevertheless been made. While the intention of AAS 3025 was to generate data within an independent project, field constraints forced a change to theatre of operations - providing core material that now fits within the scope of this project. This fieldwork produced ~130m of core from a new site on Law Dome (DSSW10k), extensions of the record at Law Dome Summit South (10m), new cores on the lower Totten Glacier (~17m) and Totten-Law Dome Trench (~15m) and Mill Is (~17m). Analysis of these cores within AAS 757 has already commenced. The DSSW10k core provides a new ~250 year record from Law Dome that will be useful in its own right, but will provide an opportunity to test both deposition processes and ice core proxy fidelity. The core comes from a location only 10km from the main coring site, but it has only half the snow accumulation rate. Comparison of the records will allow testing of the influence of snowfall rate on preservation of ice core signals. The shallow cores at Totten Glacier and Mill Is are the first records from these locations and will permit assessment of the suitability of these sites for deeper drilling. The Totten cores may also shed light on recent accumulation changes in a location where substantial surface lowering is occurring. Most of the non-field activities are directed at the first and last objectives at 1.1 (Extend time series, develop facilities), although some significant work has also been conducted towards the second and third objectives (calibration of ice core records against instrumental records, and investigating modes of variability). This has been through further investigation of the modes of variability the linking Law Dome snow accumulation with rainfall in southwest Western Australia. Calibration with both ERA-40 and NCEP reanalysis data sets and investigation of links with meridional circulation have brought this work to the point where a manuscript has been submitted on the topic. Emerging work from a recently commenced PhD student is expanding the record of water isotopes from Law Dome cores, in particular providing a time series of deuterium excess. Early results are suggestive of a new finding in which major volcanic eruptions leave a differential signal in isotopes of hydrogen and oxygen, possibly due to stratospheric oxidation processes. Work is underway to test this. Other new work toward synthesis objectives includes an interdisciplinary study tying the ice core record of methanesulphonic acid into a larger consideration of seasonal phytoplankton stress and solar irradiance. A manuscript reporting this has also been submitted. This project wound up in 2012, and was replaced by other ice-coring projects.